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Organic Chemistry, 5ed

“Visualize, Understand, Draw” helps students to move beyond memorization.

Written by two expert teachers, the Fifth Edition of Organic Chemistry is written to support all kinds of learners―whether students read the book, or use it as a reference. New “Visualize, Understand, Draw” sections help students draw molecules well, visualize how they are formed, and understand why reactions occur. The Fifth Edition has been revised to be more accessible, with a focus on the basics and more opportunities for problem-solving practice, while the robust media package helps students visualize organic chemistry.

Most students in our organic chemistry courses are not chemistry majors. We wrote this book for those students and anyone who wants a broad yet modern introduction to the subject. We stress general principles because it is impossible to memorize all the details of this vast subject. We want students to learn to make connections, recognize patterns and trends, and use a set of organizing principles to make the material more manageable and understandable. Students who will be taking standardized exams, like the MCAT, will beneft from using this text and gaining a deep understanding of the material. We also believe that the skill of critical thinking is emphasized in this text. Tis skill will help in science courses taken in the future and, more important, in future decision-making.

Organic chemistry is a highly visual subject. Organic chemists think by constructing mental pictures of molecules and communicate with each other by drawing pictures. To help students develop those same skills, we have added Visualize, Understand, Draw sections in each chapter. T hese sections highlight an important skill or concept and break it down into these three general steps with the goal of training students to use these same steps when they are solving problems.

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Contents

Chapter 1: Atoms and Molecules; Orbitals and Bonding
Chapter 2: Alkanes
Chapter 3: Alkenes and Alkynes
Chapter 4: Stereochemistry
Chapter 5: Rings
Chapter 6: Substituted Alkanes: Alkyl Halides,. Alcoholsr Aminesr Ethersr Thiols, and Thioethers
Chapter 7: Substitution Reactions: The SN2 and SN1 Reactions
Chapter 8: Elimination Reactions: The El and E2 Reactions
Chapter 9: Analytical Chemistry: Spectroscopy
Chapter 10: Electrophilic Additions to Alkenes
Chapter 11: More Additions to p Bonds
Chapter 12: Radical Reactions
Chapter 13: Dienes and the Altyl System: 2p Orbitals in Conjugation
Chapter 14: Aromaticity
Chapter 15: Substitution Reactions of Aromatic Compounds
Chapter 16: Carbonyl Chemistry 1: Addition Reactions
Chapter 17: Carboxylic Acids
Chapter 18: Derivatives of Carboxylic Acids: Acyl Compounds
Chapter 19: Carbonyl Chemistry 2: Reactions at the a Position
Chapter 20: Carbohydrates
Chapter 21: Special Topic: Bioorganic Chemistry
Chapter 22: Special Topic: Amino Acids and Polyamino Acids (Peptides and Proteins)
Chapter 23: Special Topic: Reactions Controlled by Orbital Symmetry
Chapter 24: Special Topic: Intramolecular Reactions and Neighboring Group Participation